- Title
- Kamlet-Taft solvation parameters of solvate ionic liquids
- Creator
- Dolan, Andrew; Sherman, Dylan A.; Atkin, Rob; Warr, Gregory G.
- Relation
- ARC.DP130102298 http://purl.org/au-research/grants/arc/DP130102298
- Relation
- ChemPhysChem Vol. 17, Issue 19, p. 3096-3101
- Publisher Link
- http://dx.doi.org/10.1002/cphc.201600361
- Publisher
- Wiley- V C H Verlag GmbH & Co. KGaA
- Resource Type
- journal article
- Date
- 2016
- Description
- The Kamlet–Taft solvent parameters of solvate ionic liquids (SILs) prepared from lithium salts with glyme and glycol ligands are determined. The dipolarity/polarisibilities (π*) are high, similar to those found in conventional ionic liquids. The H-bond basicities (β) depend strongly on the anion. The H-bond acidities (α) are high in both glyme and glycol SILs, indicating that the lithium is acting as a H-bond donor site. “Poor” SILs have glyme-rich and salt-rich regions. In these liquids the π* and β values are almost identical to the parent glyme or glycol, and the α values are determined by the salt alone.
- Subject
- Kamlet–Taft solvent parameters; solvate ionic liquids (SILs); lithium salts; glyme; glycol ligands
- Identifier
- http://hdl.handle.net/1959.13/1347182
- Identifier
- uon:29990
- Identifier
- ISSN:1439-4235
- Language
- eng
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